Product ID:PLPB2-3X, CUSTOM PLASMA STANDARD 10,000 PPM (SUPDAT)
MSDS Date:03/12/1996
FSC:6810
NIIN:00N084014
MSDS Number: CGRZN

SPEX CERTIPREP

203 NORCROSS AVE
METUCHEN, NJ 08840
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 908-549-7144

Preparer: SUSHA RAMANO

Cage: 04XT3

SPEX CERTIPREP INC

METUCHEN, NJ 08840 US

Telephone: 732-549-7144

Cage: 04XT3

NITRIC ACID; (HNO*3) (SARA 302/313) (CERCLA)

CAS: 7697-37-2

RTECS: QU5775000

Fraction By Weight: 2-5%

OSHA PEL 2 PPM

ACGIH TLV: 2 PPM; 4 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LEAD; (PB) (SARA 313) (CERCLA)

CAS: 7439-92-1

RTECS: OF7525000

Fraction By Weight: 0.1-1.0%

OSHA PEL N/K

ACGIH TLV: 0.15 MG/M3 DUST

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

WATER

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 92-96%

OSHA PEL N/K

ACGIH TLV: N/K

SULFIDE, ETC. CONTACT WITH STRONG BASES WILL CAUSE

RTECS: 9999999ZZ

REPRO & MYOCARDIAL EFTS. CONCENTRATED

RTECS: 9999999ZZ

THRU SKIN. CONCENTRATED NITRIC ACID VAP/MIST IS

RTECS: 9999999ZZ

PRDCES SEV BURNS WHICH MAY RSLT IN PERM DMG & VISUAL

RTECS: 9999999ZZ

IMMED, SEV & PENETRATING BURNS; CONCENTRATED SOLNS

RTECS: 9999999ZZ

YELLOWISH BROWN COLOR. VAP & MIST MAY ERODE EXPOSED

RTECS: 9999999ZZ

PAIN & BURNS OF MOUTH, ESOPHAGUS & GI TRACT. INHAL

RTECS: 9999999ZZ

& BRONCHI, CHEM PNEUMIT & PULM EDEMA. SYMPS INCL

RTECS: 9999999ZZ

OF BREATH, HEADACHE, NAUSEA & VOMITING.

RTECS: 9999999ZZ

& FULL LENGTH FACESHIELD .

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:LEAD APPEARS ON THE NAVY LIST OF OCCUP
CHEM REPRO HAZS. SEEK CONSULTATION FROM APPROP HLTH PROFESSIONALS
CONCERNING LATEST HAZARD LIST & SAFE HNDLG & EXPOS INFO . SYMPS &
HLTH HAZS FOR DILUTE NI TRIC ACID ARE EXPECTED TO BE LESS SEV THAN
EXPOS TO CONCENTRATED NITRIC ACID. HOWEVER, SINCE NITRIC (EFTS OF
OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: ACID IS IN SOLN AT 1% (OR 10,000 PPM)
OR GREATER, HLTH HAZS FOR CONCENTRATED NITRIC ACID ARE GIVEN. THIS
SOLN MAY BE HARMFUL IF INHALED, INGESTED OR CONTACTED W/SKIN OR
EYES. EXPOS TO LEAD M AY BE HARMFUL. CAN EFT BLOOD, NERVOUS SYS,
IMMUNE MECHANISMS, CAUSE CYTOGENIC CHANGES, IN ADDN TO UNDESIRABLE
(ING 5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: FLUSH W/WATER FOR AT LEAST 15 MINUTES OCCASIONALLY
LIFTING UPPER & LOWER EYELIDS. SKIN: REMOVE CONTAMINATED CLOTHING,
THEN FLUSH W/WATER FOR AT LEAST 15 MINUTES. WASH CLOTHING
THOROUGHLY BEFORE REUSE. INHAL: MOVE TO FRESH AIR. INGEST: DO NOT
INDUCE VOMITING. GET IMMED MED HELP. IF PATIENT IS CONSCIOUS, GIVE
LARGE QUANTITIES OF WATER OR MILK. IF IRRITATION CONTINUES, GET MED
ATTN IMMED.

Extinguishing Media:APPROPRIATE TO SURROUNDING FIRE CONDITIONS.
Fire Fighting Procedures:USE NIOSH APPROVED SCBA AND FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:CONCENTRATED HNO*3 IS NOT COMBUST, BUT IS
STRONG OXIDIZER & ITS HEAT OF RXN W/REDUCING AGENTS/COMBUSTIBLES
MAY CAUSE IGNIT. CAN REACT W/METALS TO RELS (SUPDAT)

Spill Release Procedures:VENT AREA. DILUTE SPILL W/WATER & NEUTRALIZE
W/SODA ASH, LIMESTONE, ETC. WIPE UP & PUT INTO SEALED CNTNR FOR
PROPER DISP. WASH SPILL SITE OFF W/WATER AFTER MATL PICK UP IS
COMPLETE. WEAR CHEM RESIST G LASSES, GLOVES & CLTHG. WEAR NIOSH
APPRVD RESP.
Neutralizing Agent:NEUTRALIZE WITH SODA ASH, LIMESTONE, ETC.

Handling and Storage Precautions:CONCENTRATED NITRIC ACID WILL ATTACK
SOME FORMS OF PLASTICS, RUBBER AND COATINGS. STORE AT ROOM
TEMPERATURE. KEEP TIGHTLY SEALED WHEN NOT IN USE.
Other Precautions:WARNING: IRRITANT, OXIDIZER, CORROSIVE. AVOID
INHALATION, INGESTION AND CONTACT WITH EYES AND SKIN. WASH
CAREFULLY AFTER USE.

Respiratory Protection:WEAR NIOSH APPROVED RESPIRATOR.
Ventilation:USE IN A CHEMICAL FUME HOOD.
Protective Gloves:CHEMICAL RESISTANT GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS (ING 13)
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER .
WEAR CHEMICAL RESISTANT CLOTHING. LAB COAT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO: OF LEAD IN 5% NITRIC ACID. EXPLO HAZ: FLAM
HYDROGEN GAS. CONCENTRATED HNO*3 REACTS EXPLO W/COMBUST ORG OR
READILY OXIDIZABLE MATLS SUCH AS ALCOHOL, WOOD, TURPENTINE, METAL
PO WDERS, HYDROGEN SULFIDE, ETC. MATL TO AVOID: SUCH AS ALCOHOL,
WOOD, TURPENTINE, METAL POWDERS, HYDROGEN (ING 4)

Spec Gravity:APPROX 1
Solubility in Water:SOLUBLE
Appearance and Odor:TRANSPARENT WITH AN ACRID ODOR.

Stability Indicator/Materials to Avoid:YES
CONCENTRATED HNO*3 IS POWERFUL OXIDIZING AGENT. IT REACTS EXPLO
W/COMBUST ORGANIC OR READILY OXIDIZABLE MATLS (SUPDAT)
Stability Condition to Avoid:STABLE UNDER NORMAL STORAGE & USE.
ELEVATED TEMPS MAY CAUSE CONTAINERS TO BURST & LIBERATE TOXIC
OXIDES OF NITROGEN.
Hazardous Decomposition Products:WILL RELEASE TOXIC NITROGEN OXIDE
FUMES AND VAPORS.

Waste Disposal Methods:CONTACT LOCAL HAZARDOUS OR CHEMICAL WASTE
DISPOSAL AGENCY FOR FEDERAL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.